om7b00626_si_001.pdf (4.91 MB)

Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe–M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination

Download (4.91 MB)
journal contribution
posted on 08.11.2017, 15:33 by Mark Abubekerov, Saeed I. Khan, Paula L. Diaconescu
The synthesis of several novel nickel­(II) and palladium­(II) ferrocene-bis­(phosphinimine) alkyl complexes containing iron–nickel and iron–palladium interactions is reported. The redox behavior of all complexes was evaluated electrochemically and chemically; in addition, reactions with weak nucleophiles, such as acetonitrile and olefins, were also investigated. DFT calculations were performed to understand the electronic structure of the alkyl metal complexes.