sc8b01498_si_001.pdf (1.23 MB)

Facile Fabrication of N‑Doped Magnetic Porous Carbon for Highly Efficient Mercury Removal

Download (1.23 MB)
journal contribution
posted on 12.07.2018 by Lijin Huang, Man He, Beibei Chen, Bin Hu
N-doped magnetic porous carbon (N-MPC) is an emerging adsorbent for water pollution control. However, high cost and multisteps procedure make the direct fabrication of N-MPCs difficult until now. Herein, highly dispersed N-MPCs were synthesized by a facial one-pot solid-state pyrolysis strategy. Heating the mixture of ZnO, Co­(OH)2, and 2-methylimidazole (HmIm), Zn/Co bimetallic ZIFs formed at the initial stages, being the primary self-template to produce N-MPCs during subsequent high-temperature treatment. By altering the pyrolysis temperature and the molar ratio of ZnO/Co­(OH)2 in the precursor, the magnetism, nitrogen content, and surface areas of N-MPCs can be easily controlled. Due to its high special surface areas and the decoration of abundant nitrogen functional groups (pyrrole-N and pyridinic-N), the optimized N-MPC-700-7/3 exhibited a superior adsorption performance for Hg2+ uptake (489 mg g–1). Moreover, the N-MPCs exhibited fast dynamics in adsorption (K2 = 0.47 g mg–1 min–1) and good chemical stability. The simple, sustainable, and impressive method provides an attractive way to manufacture efficiency MPC sorbents, and the prepared N-MPCs merit good application potential in environmental remediation.

History

Exports