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Enantioselective Total Synthesis of Valeriananoids A−C

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journal contribution
posted on 08.07.2004 by A. Srikrishna, G. Satyanarayana
The first enantioselective total synthesis of valeriananoids A−C (−)-1−3 is reported starting from the readily available monoterpene (R)-carvone, employing a tandem intermolecular Michael addition−intramolecular Michael addition−alkylation sequence and an electron-transfer-mediated 6-endo-trig cyclization as key steps.

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