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Enantioselective Copper-Catalyzed Hydroamination of Vinylarenes with Anthranils

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journal contribution
posted on 26.10.2018, 17:21 by Fang Xie, Bingxue Shen, Xingwei Li
Copper hydride-catalyzed asymmetric hydroamination of olefins with anthranils has been realized in high efficiency and high enantioselectivity, affording enantioenriched secondary arylamines tethered to a benzylic alcohol. The bifunctionality of the product has been employed in diverse derivatization reactions.

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