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Electrophilic Reaction of Ag(III) N-Confused Porphyrin with Alcohols

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journal contribution
posted on 21.05.2010 by Hua-Wei Jiang, Fei Hao, Qing-Yun Chen, Ji-Chang Xiao, Shu-Bin Liu, Yu-Cheng Gu
Experimental studies demonstrated that alcohols and amines can undergo a CF3COOAg-catalyzed nucleophilic addition at the outer CN position of Ag(III) NCPs, leading to C-3-alkoxylated Ag(III) NCPs, which supports the computational result that the CN bond on the periphery of Ag(III) NCPs is partially isolated from the 18 π-electron macrocyclic conjugation system and is the active electrophilic center.