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C-Glycosides to Fused Polycyclic Ethers. An Efficient Entry into the A−D Ring System of Gambierol

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journal contribution
posted on 08.08.2001 by Jason M. Cox, Jon D. Rainier
This Letter describes our use of C-glycosides to synthesize the A−D ring system of the marine ladder toxin gambierol in 20 steps.