la802682n_si_001.pdf (54.72 kB)

An STM Study on Nonionic Fluorosurfactant Zonyl FSN Self-Assembly on Au(111): Large Domains, Few Defects, and Good Stability

Download (54.72 kB)
journal contribution
posted on 02.12.2008 by Yongan Tang, Jiawei Yan, Xiaoshun Zhou, Yongchun Fu, Bingwei Mao
Nonionic Fluorosurfactant Zonyl FSN self-assembly on Au(111) is investigated with scanning tunneling microscopy under ambient conditions. STM reveals that the FSN forms SAMs on Au(111) with very large domain size and almost no defects. A (√3 × √3)R30° arrangement of the FSN SAM on Au(111) is observed. The SAMs show excellent chemical stability and last for at least a month in atmospheric conditions. The structure and stability of the FSN SAMs are compared with those of alkanethiols SAMs. It is expected that FSN may serve as a new kind of molecule to form SAMs for surface modification, which would benefit wider applications for various purposes.