Novel Structural and Magnetic Properties of a 1-D Iron(II)−Manganese(II) LIESST Compound Bridged by Cyanide
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posted on 2005-10-17, 00:00 authored by Shinya Hayami, Gergely Juhász, Yonezo Maeda, Toshihiko Yokoyama, Osamu SatoThe 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the
−NC−Fe−CN−Mn− heterometallic structure, has been shown to
exhibit light-induced excited spin-state trapping effects. After
illumination, anti-ferromagnetic coupling was observed between the
iron(II) (S = 2) and manganese(II) (S = 5/2) ions.
