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A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of π-Allylpalladium(II) with Indium(I) Salts

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posted on 02.03.2000, 00:00 by Shuki Araki, Toshiya Kamei, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai
A reductive transmetalation of the π-allylpalladium(II) complexes, generated in situ from a catalytic amount of a palladium(0) complex and a variety of allylic substrates, with indium(I) salts proceeded smoothly in various solvents, providing a new route for allylindium(III) reagents.