ic800864w_si_001.cif (31.03 kB)
Download file

NO2-Mediated meso-Hydroxylation of Iron(III) Porphyrin

Download (31.03 kB)
dataset
posted on 02.03.2009, 00:00 by G. J. Abhilash, Jagannath Bhuyan, Pinky Singh, Suman Maji, Kuntal Pal, Sabyasachi Sarkar
NO2 generated from NO and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.

History