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N,N‘-Dimethylformamide-Derived Products from Catalytic Oxidation of 3-Hydroxyflavone

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posted on 16.04.2007, 00:00 by Aramice Y. S. Malkhasian, Maila E. Finch, Borislava Nikolovski, Adarsh Menon, Benjamin E. Kucera, Ferman A. Chavez
The biomimetic conversion of 3-hydroxyflavone in the presence of a copper(II) catalyst, dioxygen, and N,N-dimethylformamide to oxidation products as well as two previously unreported solvent-derived products is seen. The two solvent-derived products were characterized, and their crystal structures were determined.