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[W(bipy)(CN)6]: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes

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posted on 07.05.2012, 00:00 by Maria-Gabriela Alexandru, Diana Visinescu, Augustin M. Madalan, Francesc Lloret, Miguel Julve, Marius Andruh
The first 3d–4f–5d heterotrimetallic complexes using [WV(bipy)­(CN)6] as a metalloligand were synthesized (bipy = 2,2′-bipyridine). The structural and magnetic properties of three [CuIILnIIIWV] complexes (Ln = Gd, Ho, Tb) are discussed.