ic300544m_si_002.cif (79.8 kB)
[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes
datasetposted on 2012-05-07, 00:00 authored by Maria-Gabriela Alexandru, Diana Visinescu, Augustin M. Madalan, Francesc Lloret, Miguel Julve, Marius Andruh
The first 3d–4f–5d heterotrimetallic complexes using [WV(bipy)(CN)6]− as a metalloligand were synthesized (bipy = 2,2′-bipyridine). The structural and magnetic properties of three [CuIILnIIIWV] complexes (Ln = Gd, Ho, Tb) are discussed.