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[W(bipy)(CN)<sub>6</sub>]<sup>−</sup>: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First Cu<sup>II</sup>Ln<sup>III</sup>W<sup>V</sup> Trinuclear Complexes

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posted on 2012-05-07, 00:00 authored by Maria-Gabriela Alexandru, Diana Visinescu, Augustin M. Madalan, Francesc Lloret, Miguel Julve, Marius Andruh
The first 3d–4f–5d heterotrimetallic complexes using [W<sup>V</sup>(bipy)­(CN)<sub>6</sub>]<sup>−</sup> as a metalloligand were synthesized (bipy = 2,2′-bipyridine). The structural and magnetic properties of three [Cu<sup>II</sup>Ln<sup>III</sup>W<sup>V</sup>] complexes (Ln = Gd, Ho, Tb) are discussed.

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