[W(bipy)(CN)<sub>6</sub>]<sup>−</sup>: A Suitable
Metalloligand in the Design of Heterotrimetallic Complexes. The First
Cu<sup>II</sup>Ln<sup>III</sup>W<sup>V</sup> Trinuclear Complexes
posted on 2012-05-07, 00:00authored byMaria-Gabriela Alexandru, Diana Visinescu, Augustin M. Madalan, Francesc Lloret, Miguel Julve, Marius Andruh
The first 3d–4f–5d heterotrimetallic complexes
using
[W<sup>V</sup>(bipy)(CN)<sub>6</sub>]<sup>−</sup> as a metalloligand
were synthesized (bipy = 2,2′-bipyridine). The structural and
magnetic properties of three [Cu<sup>II</sup>Ln<sup>III</sup>W<sup>V</sup>] complexes (Ln = Gd, Ho, Tb) are discussed.