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[Cu(C24H22N4O3)]·CH2Cl2:  A Discrete Breathing Metallamacrocycle Showing Selective and Reversible Guest Adsorption with Retention of Single Crystallinity

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posted on 2007-02-14, 00:00 authored by Yu-Bin Dong, Qiang Zhang, Li-Li Liu, Jian-Ping Ma, Bo Tang, Ru-Qi Huang
A discrete, breathing metallamacrocycle Cu2L2 exhibits reversible and selective size-, shape-, and number-dependent guest adsorption with retention of single crystallinity. The system can exclusively recognize CHCl3 molecules from mixed CH2Cl2/CHCl3 vapor.

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[Cu(C24H22N4O3)]·CH2Cl2:  A Discrete Breathing Metallamacrocycle Showing Selective and Reversible Guest Adsorption with Retention of Single Crystallinity
Journal of the American Chemical SocietyJournal of the American Chemical Society

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breathing metallamacrocycle Cu 2L exhibitsDiscrete Breathing MetallamacrocyclecrystallinityguestCHCl 3 moleculesadsorptionSelectiveCH 2Cl vaporretentionReversible Guest AdsorptionSingle CrystallinityARetention

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