sc8b03486_si_002.zip (12.89 MB)
Zinc Battery Driven by an Electro-Organic Reactor Cathode
dataset
posted on 2018-09-20, 00:00 authored by Mahesh Itagi, Shateesh Battu, Mruthyunjayachari
Chattanahalli Devendrachari, Zahid M. Bhat, Alagar Raja Kottaichamy, Deepraj Pandit, Manu Gautam, Ravikumar Thimmappa, Lokesh Koodlur Sannegowda, Musthafa Ottakam ThotiylSynthesis
of organic molecules by utilizing the principles of electrochemistry
satisfies 9 out of the 12 postulates of green chemistry, conferring
electrochemical synthetic methodologies with clean, safe, and green
tags. However, electro-organic synthesis is a heterogeneous interfacial
reaction demanding significant driving force in terms of voltage or
current. Here, we demonstrate an unusual route for electro-organic
synthesis during electricity generation in a battery, where the positive
half-cell is designed to function as an organic reactor generating
useful chemicals and fuel molecules. The proposed electro-organic
synthesizer Zn battery couples organic synthesis with power production
during discharge chemistry, thereby demonstrating its tremendous potential
in the sustainable energy landscape.