Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization
datasetposted on 14.09.2015 by Liang Liu, Weizhi Geng, Qi Yang, Wen-Xiong Zhang, Zhenfeng Xi
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
Two examples of mixed alkenyl/aryl organocopper(I) aggregates possessing conjugated alkenyl/aryl C–Cu bonds were synthesized by transmetalation of zirconaindenes with CuCl. Single-crystal X-ray structural analysis revealed tetrameric and hexameric structures. Butadienyl copper(I) aggregates were also synthesized and structurally characterized for further comparison. The preliminary reaction chemistry of the copper(I) aggregates was studied.