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Download fileVisible-Light Driven Photocascade Catalysis: Union of N,N‑Dimethylanilines and α‑Azidochalcones in Flow Microreactors
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posted on 2017-01-30, 00:00 authored by Satheesh Borra, D. Chandrasekhar, Susanta Adhikary, Sandeep Rasala, Sabapathi Gokulnath, Ram Awatar MauryaN,N-Dimethylanilines were coupled
with α-azidochalcones using visible-light driven Ru(bpy)3(PF6)2 catalyzed photocascade continuous
flow microfluidic approach that involves the creation of one C–C
and two C–N new bonds. The reaction involves dual photocatalysis
ensuing two sp3 C–H bond functionalization of N,N-dimethylanilines. To explore the scope
of the reaction, 20 different 1,3-diazabicyclo[3.1.0]hexanes were
synthesized in good yields (55–71%).
