Versatile Coordination Mode of LiNaB8O13 and α- and β‑LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups
datasetposted on 19.01.2016 by Donghai An, Qingrong Kong, Min Zhang, Yun Yang, Danni Li, Zhihua Yang, Shilie Pan, Huimin Chen, Zhi Su, Yi Sun, Miriding Mutailipu
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
Three new alkali-metal mixed borates, LiNaB8O13, α-LiKB8O13, and β-LiKB8O13, containing a 3∞[B8O13] three-dimensional network have been successfully synthesized. Their fundamental building block is [B8O16]8– formed by the vertex-sharing [B5O10]5– and [B3O7]5– groups, which are topologically identical when they are considered as four-connected nodes. The viewpoints give us a feasible way to investigate the versatile structure assembly of borates with a complex network.