cg034084+_si_002.cif (27.94 kB)
Download fileTwo Three-Dimensional Metal−Organic Frameworks from Secondary Building Units of Zn8(OH)4(O2C−)12 and Zn2((OH)(O2C−)3: [Zn2(OH)(btc)]2(4,4‘-bipy) and Zn2(OH)(btc)(pipe)
dataset
posted on 06.08.2003, 00:00 authored by Zhan Shi, Guanghua Li, Lei Wang, Lu Gao, Xiaobo Chen, Jia Hua, Shouhua FengTwo three-dimensional metal−organic frameworks, [Zn2(OH)(btc)]2(4,4‘-bipy) and Zn2(OH)(btc)(pipe) (btc
= 1,3,5-benzenetricarboxylate; 4,4‘-bipy = 4,4‘-bipyridine; pipe = piperazine) with respectively the largest pure zinc clusters
of Zn8(OH)4(O2C−)12 and interpenetrating networks, were synthesized by hydrothermal reactions and characterized by
single-crystal X-ray diffraction.