cg034084+_si_002.cif (27.94 kB)

Two Three-Dimensional Metal−Organic Frameworks from Secondary Building Units of Zn₈(OH)₄(O₂C−)₁₂ and Zn₂((OH)(O₂C−)₃: [Zn₂(OH)(btc)]₂(4,4‘-bipy) and Zn₂(OH)(btc)(pipe)

dataset

posted on 06.08.2003, 00:00 authored by Zhan Shi, Guanghua Li, Lei Wang, Lu Gao, Xiaobo Chen, Jia Hua, Shouhua Feng

Two three-dimensional metal−organic frameworks, [Zn₂(OH)(btc)]₂(4,4‘-bipy) and Zn₂(OH)(btc)(pipe) (btc = 1,3,5-benzenetricarboxylate; 4,4‘-bipy = 4,4‘-bipyridine; pipe = piperazine) with respectively the largest pure zinc clusters of Zn₈(OH)₄(O₂C−)₁₂ and interpenetrating networks, were synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction.