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Two Nanocage-Based Metal–Organic Frameworks with Mixed-Cluster SBUs and CO2 Sorption Selectivity

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posted on 21.09.2015, 00:00 by Bo Liu, Wei-Ping Wu, Lei Hou, Zhi-Sen Li, Yao-Yu Wang
Two nanocage-based metal–organic frameworks respectively built on two and three types of clusters with diisophthalate ligand were constructed, displaying unprecedented (3,4,6)-connected nets, unusual nanocages, and new bipaddle-wheel tetranuclear cluster, as well as highly selective CO2 capture.