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Total Syntheses of Chelidonine and Norchelidonine via an Enamide–Benzyne–[2 + 2] Cycloaddition Cascade

Name: Total Syntheses of Chelidonine and Norchelidonine via an Enamide–Benzyne–[2 + 2] Cycloaddition Cascade
Published: 2012-06-01T00:00:00+00:00
License: https://creativecommons.org/licenses/by-nc/4.0/
Keywords: CascadeTotal, pericyclic, Total Syntheses, intramolecular, enamide, cycloaddition, Norchelidonine, Diel, norchelidonine, chelidonine, cascade, synthese, Enamide, Chelidonine, Cycloaddition

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posted on 2012-06-01, 00:00 authored by Zhi-Xiong Ma, John B. Feltenberger, Richard P. Hsung

Total syntheses of chelidonine and norchelidonine featuring an enamide–benzyne–[2 + 2] cycloaddition initiated cascade is described. The cascade includes a pericyclic ring-opening and intramolecular Diels–Alder reaction.

Total Syntheses of Chelidonine and Norchelidonine via an Enamide–Benzyne–[2 + 2] Cycloaddition Cascade

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