Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands

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posted on 2017-01-17, 13:40 authored by Andrew Brown, Mohamed Saber, Willem Van den Heuvel, Kelsey Schulte, Alessandro Soncini, Kim R. Dunbar

The titanium(III) cyanide compound [Et₄N][Tp*Ti(CN)₃] ([Et₄N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = ¹/₂ paramagnet and that it exhibits significant temperature-independent paramagnetism.

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exhibit Tp Member Magnetic data trigonally Cyanide Ligands Scorpionate molecule dimethyltrispyrazolylhydroborate compound ab initio calculations Trigonal Building Blocks temperature-independent paramagnetism cyanide Et tetraethylamonium

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CC BY-NC 4.0

Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands

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