ic051829n_si_002.cif (24.54 kB)
Thermochromic Triangular [MCo2] (M = Rh, Ir, Ru) Clusters Containing a Planar Metalladithiolene Ring in η3 Coordination
dataset
posted on 2006-01-09, 00:00 authored by Norikiyo Nakagawa, Teppei Yamada, Masaki Murata, Manabu Sugimoto, Hiroshi NishiharaThe first series of triangular cluster complexes of [MCo2] (M =
Rh, Ir, Ru) with a planar metalladithiolene ring coordinating in the
η3-bonding mode were synthesized, and the crystal structures,
spectral and electrochemical properties, and thermochromism of
these complexes were revealed.
