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Thermochromic Triangular [MCo2] (M = Rh, Ir, Ru) Clusters Containing a Planar Metalladithiolene Ring in η3 Coordination

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posted on 2006-01-09, 00:00 authored by Norikiyo Nakagawa, Teppei Yamada, Masaki Murata, Manabu Sugimoto, Hiroshi Nishihara
The first series of triangular cluster complexes of [MCo2] (M = Rh, Ir, Ru) with a planar metalladithiolene ring coordinating in the η3-bonding mode were synthesized, and the crystal structures, spectral and electrochemical properties, and thermochromism of these complexes were revealed.