TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest Inclusion
datasetposted on 27.12.2006 by Satoru Shimomura, Ryotaro Matsuda, Takashi Tsujino, Takashi Kawamura, Susumu Kitagawa
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
A three-dimensional coordination framework constructed with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) diainon has been synthesized and structurally characterized. This open framework possessing a highly electron-rich surface has an optical sensing cavity for several aromatics with crystal-to-crystal transformation and strong accommodation, which are based on a charge-transfer interaction with them.