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Synthesis of Ultrahighly Electron-Deficient Pyrrolo[3,4‑d]pyridazine-5,7-dione by Inverse Electron Demand Diels–Alder Reaction and Its Application as Electrochromic Materials

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posted on 19.12.2014, 00:00 authored by Qun Ye, Wei Teng Neo, Ching Mui Cho, Shuo Wang Yang, Tingting Lin, Hui Zhou, Hong Yan, Xuehong Lu, Chunyan Chi, Jianwei Xu
A new electron acceptor 6-alkylpyrrolo­[3,4-d]­pyridazine-5,7-dione (PPD) with a very low LUMO level has been synthesized via a challenging inverse electron demand Diels–Alder reaction between thiophene and furan-decorated tetrazine substrates and an electron-deficient 1-alkyl-1H-pyrrole-2,5-dione unit. The PPD monomer has been incorporated into a series of donor–acceptor-type conjugated polymers as electrochromic materials with good optical contrast, fast switching speed, and high coloration efficiency.

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