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Synthesis of Potassium−Magnesium Ate Complexes with a Bulky Diamido Ligand

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posted on 14.09.2009, 00:00 by Chengfu Pi, Li Wan, Yingying Gu, Haoyu Wu, Chengxi Wang, Wenjun Zheng, Linhong Weng, Zhenxia Chen, Xiaodian Yang, Limin Wu
Two mixed potassium−magnesium complexes (magnesiates) with novel structural conformations were prepared by the reduction of a neutral magnesium ([(μ-Mg){η21-Me2Si(NDipp)2}]2) complex bearing bulky diamido ligands with metallic potassium.