American Chemical Society
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Synthesis of Polynitroxides Based on Nucleophilic Aromatic Substitution

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posted on 2010-08-20, 00:00 authored by Olaf Zeika, Yongjun Li, Steffen Jockusch, Gerard Parkin, Aaron Sattler, Wesley Sattler, Nicholas J. Turro
The scope and limitations of the synthesis of polynitroxides by nucleophilic substitution of electron-deficient fluorinated aromatic compounds are described. The method provides a facile route to the formation of polynitroxides exhibiting strong electron exchange between nitroxide groups.