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Synthesis of Polycyclic Molecules by Double C(sp2)−H/C(sp3)−H Arylations with a Single Palladium Catalyst

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posted on 01.04.2011, 00:00 authored by Cathleen Pierre, Olivier Baudoin
Polycyclic molecules were obtained in good yields by double C(sp2)−H/C(sp3)−H arylations mediated by a single palladium/phosphine catalyst. Both double intermolecular/intramolecular and intramolecular/intramolecular C−C couplings were performed successfully, which indicates that this concept has a broad applicability for the rapid construction of molecular complexity.