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Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5 Complex

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posted on 2008-06-09, 00:00 authored by Maren Bode, Gregor Schnakenburg, Peter G. Jones, Rainer Streubel
A facile and highly stereoselective synthesis of novel O,P,C-cage complexes via thermal C−O ring opening of an oxaphosphirane W(CO)5 complex is described. All compounds were unambiguously characterized by elemental analysis, multinuclear NMR, IR, MS, and single-crystal X-ray diffraction studies.

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