ol0167210_si_002.cif (96.88 kB)

Synthesis of Griseolic Acid B by π-Face-Dependent Radical Cyclization

Download (96.88 kB)
dataset
posted on 04.10.2001, 00:00 by Spencer Knapp, Machender R. Madduru, Zhijian Lu, Gregori J. Morriello, Thomas J. Emge, George A. Doss
Radical cyclization of 6 affords the bicyclic vinyl ether 9 with the appropriate stereochemistry for elaboration (seven steps) to griseolic acid B (1).

History

Exports