ol6b00727_si_001.cif (873.67 kB)
Download fileSynthesis of 1H‑Indazoles from Imidates and Nitrosobenzenes via Synergistic Rhodium/Copper Catalysis
dataset
posted on 15.04.2016, 16:03 authored by Qiang Wang, Xingwei LiNitrosobenzenes have been used as
a convenient aminating reagent
for the efficient synthesis of 1H-indazoles via rhodium
and copper catalyzed C–H activation and C–N/N–N
coupling. The reaction occurred under redox-neutral conditions with
high efficiency and functional group tolerance. Moreover, a rhodacyclic
imidate complex has been identified as a key intermediate.