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Synthesis and Structure of a Trinuclear Platinum Complex with μ3-Silylyne Ligands Derived from a Disilane

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posted on 24.08.2009, 00:00 authored by Hidekazu Arii, Makiko Takahashi, Masato Nanjo, Kunio Mochida
The platinum complex [Pt(dppe)(η2-C2H4)] (1) reacted with the disilane H2SiMeSiMe3, affording the bis(μ-silylyne)triplatinum complex [Pt3(dppe)33-SiMe)2] (4) by a stepwise Si−H and Si−Si bond activation.