American Chemical Society
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Synthesis and Structure of New [3]Silametallocenophanes of Group 8 Metals

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posted on 2012-09-10, 00:00 authored by Holger Braunschweig, Alexander Damme, Kai Hammond, Julian Mager
The synthesis and characterization of new [3]­silametallocenophanes of the group 8 metals via salt elimination is presented. Thereby, new [3]­silaferrocenophanes as well as the first [3]­silametallocenophanes of the heavier metals ruthenium and osmium could be synthesized and characterized. Also, the first solid-state structure of a [3]­silaferrocenophane was determined by X-ray crystallographic analysis.