Synthesis and Structure of New Silametallocenophanes of Group 8 Metals
datasetposted on 2012-09-10, 00:00 authored by Holger Braunschweig, Alexander Damme, Kai Hammond, Julian Mager
The synthesis and characterization of new silametallocenophanes of the group 8 metals via salt elimination is presented. Thereby, new silaferrocenophanes as well as the first silametallocenophanes of the heavier metals ruthenium and osmium could be synthesized and characterized. Also, the first solid-state structure of a silaferrocenophane was determined by X-ray crystallographic analysis.