ol047943b_si_001.cif (67 kB)
Synthesis and Properties of gem-(Difluorocyclopropyl)amine Derivatives of Bicyclo[n.1.0]alkanes
dataset
posted on 2004-12-09, 00:00 authored by Ireneusz Nowak, John F. Cannon, Morris J. RobinsGeneration of difluorocarbene(carbenoid) in the presence of enamines derived from cyclic ketones results in overall insertion of CF2 to produce
bicyclic difluorocyclopropylamines. These adducts are very weakly basic, and their thermal stabilities vary markedly with their structures.