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Synthesis and Characterization of a 1-D Porous Barium Carboxylate Coordination Polymer, [Ba(HBTB)] (H3BTB = Benzene-1,3,5-trisbenzoic Acid)

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posted on 05.12.2011, 00:00 authored by Maw Lin Foo, Satoshi Horike, Susumu Kitagawa
The synthesis and characterization of [Ba­(HBTB)] is reported. This is the first porous framework synthesized with barium using carboxylate ligands. The framework has robust microporous character (Langmuir surface area of 879 m2 g–1) and possesses unsaturated metal sites when fully desolvated.