Synthesis and Characterization of Novel Iron(0) Complexes Derived from α,β-Unsaturated-Ketone Analogues with β-Positioned Heteroatoms Containing Covalent and Coordination Bonds
datasetposted on 02.09.2000, 00:00 by Fernando Ortega-Jiménez, M. Carmen Ortega-Alfaro, José G. López-Cortés, René Gutiérrez-Pérez, Rubén A. Toscano, Luis Velasco-Ibarra, Eduardo Peña-Cabrera, Cecilio Alvarez-Toledano
Synthesis of novel mono- and dinuclear complexes of Fe(0) are reported displaying both coordination and organometallic bonds. 5−11 were prepared by allowing the new ligands 1−4 to react with Fe2(CO)9. The structures of the complexes were determined by spectroscopic methods (IR, MS, HR-MS, 1H and 13C NMR) and confirmed by single-crystal X-ray analysis.