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Synthesis and Characterization of Heavier Group 13 Element Ferrocenophanes:  The First Gallium-Bridged [1]Ferrocenophane and an Unusual Indium Species

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posted on 29.08.2005, 00:00 by Jörg A. Schachner, Clinton L. Lund, J. Wilson Quail, Jens Müller
On the basis of our previous results with aluminum, we herein report the synthesis of the first gallium-bridged [1]ferrocenophane. The attempt to synthesize the respective indium compound resulted in an unusual ferrocenophane containing an In−(μ-Cl)2−In group in the bridging position. All compounds have been characterized by NMR spectroscopy and single-crystal X-ray structural determination.