ol026281s_si_002.cif (78.03 kB)

Synthesis, X-ray Structure, and Properties of the Singly Bonded C60 Dimer Having Diethoxyphosphorylmethyl Groups Utilizing the Chemistry of C602-

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posted on 21.06.2002, 00:00 by Fuyong Cheng, Yasujiro Murata, Koichi Komatsu
A singly bonded C60 dimer having a diethoxyphosphorylmethyl group on each C60 cage was obtained by the reaction of C602- dianion with diethyl iodomethylphosphonate followed by the treatment with iodine. The precise structure of the dimer was determined for the first time by X-ray crystallography, and its homolytic dissociation as well as spectroscopic and electrochemical properties were clarified.