Synthesis, Structure, and Properties of a Dimeric Chromium(II) Pyrazolato Complex with a Long Chromium−Chromium Distance. Maintenance of a Dimeric Structure in Solution and Interconversion between Dimeric and Monomeric Structures
dataset
posted on 2006-07-10, 00:00 authored by Oussama M. El-Kadri, Mary Jane Heeg, Charles H. WinterThe synthesis, solid-state structure, and solution structure of
Cr2(tBu2pz)4 are described. This complex is obtained by sublimation
of the monomeric species Cr(tBu2pz)2(4-tBupy)2 and contains long
chromium−chromium distances that are enforced by the divergent
nature of the pyrazolato ligands.
