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Synthesis, Structural Characterization, and Spectroscopy of the Cadmium−Cadmium Bonded Molecular Species Ar‘CdCdAr‘ (Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2)

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posted on 2006-11-29, 00:00 authored by Zhongliang Zhu, Roland C. Fischer, James C. Fettinger, Eric Rivard, Marcin Brynda, Philip P. Power
The synthesis and first structural characterization of a cadmium−cadmium bonded molecular compound Ar‘CdCdAr‘ (Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2) are reported. The existence of the Cd−Cd bond was established by 113Cd NMR spectroscopy and X-ray diffraction (Cd−Cd = 2.6257(5) Å). Like its group 12 analogue Ar‘ZnZnAr‘, DFT calculations showed that Ar‘CdCdAr‘ had significant p-character in the Cd−Cd σ-bonding HOMO.

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