Synthesis, Optical, and Redox Properties of Regioisomeric Benzoheterocycles-Fused Pyrene
datasetposted on 25.12.2018 by Anabella Mocanu, Rózsa Szűcs, Elsa Caytan, Thierry Roisnel, Vincent Dorcet, Pierre-Antoine Bouit, László Nyulászi, Muriel Hissler
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
A new synthetic route toward the synthesis of benzo[b]phospholes- and benzo[b]siloles-fused pyrenes using a transition metal-catalyzed C–H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.