jo8b02884_si_003.cif (417.5 kB)

Synthesis, Optical, and Redox Properties of Regioisomeric Benzoheterocycles-Fused Pyrene

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posted on 25.12.2018 by Anabella Mocanu, Rózsa Szűcs, Elsa Caytan, Thierry Roisnel, Vincent Dorcet, Pierre-Antoine Bouit, László Nyulászi, Muriel Hissler
A new synthetic route toward the synthesis of benzo­[b]­phospholes- and benzo­[b]­siloles-fused pyrenes using a transition metal-catalyzed C–H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.