jo8b02884_si_001.cif (570.68 kB)

Synthesis, Optical, and Redox Properties of Regioisomeric Benzoheterocycles-Fused Pyrene

Download (570.68 kB)
posted on 25.12.2018 by Anabella Mocanu, Rózsa Szűcs, Elsa Caytan, Thierry Roisnel, Vincent Dorcet, Pierre-Antoine Bouit, László Nyulászi, Muriel Hissler
A new synthetic route toward the synthesis of benzo­[b]­phospholes- and benzo­[b]­siloles-fused pyrenes using a transition metal-catalyzed C–H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.