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Synthesis, Crystal Structure, Magnetic Properties, and Stability of the Manganese-Rich “Mn3AlC” κ Phase

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posted on 17.01.2017, 13:49 authored by Hannes Dierkes, Jan van Leusen, Dimitri Bogdanovski, Richard Dronskowski
κ-carbides of varying composition, seemingly responsible for age hardening in high-Al steel alloys, have been detected to precipitate both at grain boundaries and in the bulk grain of steels. Herein we report the bulk-phase synthesis of “Mn3AlC” by arc plasma sintering and rapid solidification. Single crystals have been found suitable for X-ray diffraction using Mo radiation and yield a lattice parameter of a = 3.875(2) Å. We find a mixed occupation of the 1a position by Al and Mn, which, together with the C position being fully occupied, leads to the actual composition Mn3.1Al0.9C. Additional energy-dispersive X-ray–scanning electron microscopy measurements support the composition and corroborate the homogeneity. SQUID data collected on the polycrystalline ferromagnetic sample exhibit a Curie temperature of about 295 ± 13 K and a soft magnetic behavior. The small but significant nonstoichiometry on 1a leads to a slightly larger lattice parameter, a higher electron count, and, thus, a lowered density of states at the Fermi level, indicative of increased phase stability.