om501055f_si_002.cif (909.62 kB)
Syntheses and Structures of Stable 1‑Aminoalumole Derivatives
dataset
posted on 2014-12-08, 00:00 authored by Tomohiro Agou, Tatsuya Wasano, Takahiro Sasamori, Norihiro TokitohReaction
of an isolable 1-bromoalumole with LiN(SiMe3)2 in toluene afforded a lithium 1,1-diaminodialumoluide, while in
THF the corresponding 1-aminoalumole–THF complex was obtained.
These amino-substituted alumole derivatives are characterized by X-ray
crystallographic analysis and NMR spectroscopy. The lithium 1,1-diaminoalumoluide
and the 1-aminoalumole–THF complex were converted to each other
by ligand exchange reactions.