Syntheses and Anion Binding Capabilities of Bis(diarylboryl) Ferrocenes and Related Systems
datasetposted on 13.05.2013 by Michael J. Kelly, Alexander E.J. Broomsgrove, Ian R. Morgan, Inke Siewert, Philip Fitzpatrick, Jessica Smart, Dragoslav Vidovic, Simon Aldridge
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si–F–B bridging motif.