posted on 2019-07-30, 18:40authored byPierre-Luc
T. Boudreault, Miguel A. Esteruelas, Erik Mora, Enrique Oñate, Jui-Yi Tsai
The complex Ir(acac){κ2-C,N-[C6BrH3-py]}{κ2-C,N-[C6H4-py]} (2) is a green emitter,
which displays short lifetimes (0.9–4.9 μs) and quantum
yields of 0.32 in poly(methyl methacrylate) films at 5 wt % and 0.41
in 2-methyltetrahydrofuran at room temperature. Its Pd(OAc)2/4 PPh3-catalyzed cross-coupling reactions with RB(OH)2 afford Ir(acac){κ2-C,N-[C6RH3-py]}{κ2-C,N-[C6H4-py]} (R = Me (3), Ph (4)), which show almost identical emissions with quantum yields
in the range 0.98–0.82.