ic701463h_si_005.cif (24.06 kB)

Supramolecular Isomerism with Polythreaded Topology Based on [Mo8O26]4- Isomers

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posted on 21.01.2008, 00:00 by Ya-Qian Lan, Li, Xin-Long Wang, Kui-Zhan Shao, Zhong-Min Su, En-Bo Wang
Two compounds, namely, [Cu(bbi)]2[Cu2(bbi)2(δ-Mo8O26)0.5][α-Mo8O26]0.5 (1) and [Cu(bbi)][Cu(bbi)(θ-Mo8O26)0.5] (2), where bbi is 1,1‘-(1,4-butanediyl)bis(imidazole), were synthesized under hydrothermal conditions at different pH values. Their crystal structures were determined by X-ray diffraction. Compounds 1 and 2 are supramolecular isomers with a polythreaded topology based on octamolybdate building blocks.