Substituent Effects on Singlet Exciton Fission in Polycrystalline Thin Films of Cyano-Substituted Diaryltetracenes
datasetposted on 10.08.2017, 00:00 by Eric A. Margulies, Nicolas Kerisit, Przemyslaw Gawel, Catherine M. Mauck, Lin Ma, Claire E. Miller, Ryan M. Young, Nils Trapp, Yi-Lin Wu, François Diederich, Michael R. Wasielewski
Cyano-substituted tetracenes (5,11-dicyano-6,12-diphenyltetracene, Tet) undergo exoergic singlet fission (SF), a spin-allowed photophysical process that generates a pair of triplet excitons from one singlet exciton. To elucidate substituent effects on SF, we have measured the SF dynamics and triplet yields of thin films, formed by Tet bearing hydrogen (H), methyl (Me), fluoro (F), and trimethylsilyl (TMS) substituents on the p-phenyl positions and on the 3 and 9 positions of the tetracene core, by time-resolved spectroscopy in the vis-NIR and IR regions. The H-, Me-, and F-Tet display strong intramolecular electronic coupling (π–π distances <4 Å), and SF gives high triplet exciton yields up to 200% (quantitative). In addition, a charge-transfer state mediates SF in F-Tet films, while H-Tet and Me-Tet show no evidence for such a state. Correlations between the SF yields and the crystal structure show that chromophore slippage along both their short and long axes allows efficient SF and that a large degree of π contact between the chromophores is not necessary for rapid and efficient SF in the solid state. As expected, the large interchromophore distance in TMS-Tet (>4 Å) reduces its SF triplet yield to about 60%.
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interchromophore distancetime-resolved spectroscopy9 positionschromophore slippageF-Tet filmsπ contacttriplet excitonssinglet excitonSubstituent Effectsexoergic singlet fissionelucidate substituent effectscharge-transfer state mediates SFcrystal structure showTMSspin-allowed photophysical processSF triplettetracene coreMe-Tet showtriplet yieldsSinglet Exciton FissionSF yieldsIR regionsphenyl positionsSF dynamicsF-Tet displaytriplet exciton yields