Structure-Directing Self-Assembly, Structures and Characterization of Four d0‑Transition Metal Oxide/Fluoride Compounds Constructed with Imidazole/1-Methylimidazole/1-Vinylimidazole and Copper(II)/Zinc(II)
datasetposted on 06.02.2013 by Yi-Ping Tong, Guo-Tian Luo, Jin Zhen, You Shen, Hui-Ru Liu
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
Four d0 transition metal oxide/fluoride compounds of V(V), Mo(VI), and Ti(IV), with the “2D layer”, “1D zigzag chain”, “1D linear chain”, and “0D cluster” structures, have been hydrothermally synthesized, by the structure-directing self-assembly of Meimi/Viimi/imi ligands, and other transition metal Zn(II)/Cd(II) ions. The structure-directing property of d0 transition metal oxide/fluoride anions is responsible for the tunable syntheses of novel inorganic solids with structural diversities, while the distortion of the d0 transition metal oxide/fluoride polyhedrons, owing to the second-order Jahn–Teller (SOJT) effect, is the key to engineering the structure-directing property.