om050835o_si_001.cif (108.95 kB)

Structural Aspects of Trimethylsilylated Branched Group 14 Compounds

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posted on 19.12.2005, 00:00 by Judith Baumgartner, Roland Fischer, Jelena Fischer, Andreas Wallner, Christoph Marschner, Ulrich Flörke
Some newly synthesized compounds of the type [(Me3Si)3X1X2(SiMe3)3] (X1, X2 = Si, Ge, or Sn) together with some related compounds bearing triisopropylsilyl or -stannyl groups are characterized by single-crystal X-ray crystallography. The structural data are compared to similar compounds already known. The interaction of silyl groups connected to different central atoms such as Si, Ge, and Sn is analyzed.